SCIENCE-WORLD-CHEMISTRY

[ PYROTECHNICS ]

SW-News

Science-World invites you to a fantastic and amazing world of fire and explosion ! Follow the steps listed below and enjoy the dangerous but beautiful side of chemistry ! If you are just getting started, try to get hold of as much information on the subject as you can, and read it carefully. If it is explosives you are interested in, make sure you read up on the theory behind explosives: LITERATURE New page containing lots of experiments on pyrotechnics and explosives.
Warning ! Some of these experiments are only for experienced people. To avoid harm or even sudden injure, follow the security instructions listed above each text.
Read this first before
you start the experiments !
   

THE LIST OF EXPERIMENTS INTRODUCING
PYROTECHNICS

Type of experiment + Effect Instructions + Experiences danger
symbols
Rules + Warnings + Links
Safety fuse
(slow match)

Use this essential component to ignite some of the explosives listed below. Keep in mind that other safety steps have to be set up before starting the fuse.

Ingredients:
??????????

Before using this helpful component it is really important to know how to treat it.
A matter of fact is that safety fuses burn up in comparatively different rates. Always test the burning speed of your own produced cords because of the paste's varying coarseness.
NOTE: It is only a question of time when things happen too fast and cause unexpected injurious results.
Some explosives must not be ignited directly. Therefore it is a good advice to use safety fuses.

Alexej's powerful 'heat-bomb'

This powerful and destructive substance evaporates everything and itself in a given range. As a nuke-like bomb it emits an unpleasant white and bluish flash of light blinding its viewers. The heat of 5000°C burns off everything and sets free a high pressured gas that creates a deafening detonation.

Ingredients:
???????????
Expl Never (!) keep this substance in wet or even humid places. Keep it in a secure bottle in a dry and cold place ! Beware of the temperature rising above 70°C ! If it suddenly gets warmer than your body temperature, it will be better to cancel the whole experiment. Use it in a secure place. Beware of the blinding light - use protective goggles and gloves. 5000 °C is an average temperature in this case.

If you want to find out more about fine aluminium-powder, link to:
http://www.argonide.com

nitrocellulose
(nitric ester of cellulose)
guncotton
(Schiessbaumwolle)

This quite explosive cotton-like substance burns off like lightning in contact with air and heat ! Fire, pressure or primary explosives will be sufficient to get a satisfying result !

Ingredients:
Wikipedia
Experimentalchemie
Chemie am Landesinstitut für Pädagogik und Medien, Saarbrücken, Versuche zur Anorganischen Chemie (Sekundarstufe I)Versuch 98

Pure cotton, nitrating acid (HNO3 + H2SO4)

20 ml of concentrated nitric acid with 40 ml of concentrated sulfuric acid. The cotton (2 g) being influenced by the prepared nitric acid about 15 min.

Cleanse the received product until it is free of acid. It should be washed with water until it gets neutral. Dry guncotton to introduce its reactivity.

As its name introduces the military function, guncotton was once used as a initial detonating agent for guns etc.

 

Expl Never use guncotton in large quantities ! Nitrocellulose is very evaporative because of its high combustibility. It burns off without nearly any residues. Beware of its explosiveness. Once stuffed into a tight metallic container a grenade-like bomb will be the hazardous result. Use only for shooting experiments and the purpose of high pressure. It is even better to study it for the very first time in order to learn its powers: burn it off in open conditions.

Deutscher Bildungsserver

Universität Frankfurt, Schauvorlesung

Dialyse mit Schießbaumwolle

black powder

 

Ingredients:

Wikipedia
Chemie am Landesinstitut für Pädagogik und Medien, Saarbrücken
, Versuche zur Anorganischen Chemie (Sekundarstufe I)Versuch 107  

Universität Siegen

Universität Bayreuth:
Chemie der Feuerwerkskörper, Didaktik der Chemie

Sternblog

75 % KNO3, 10 % S, 15 % C (Potassium nitrate, pure sulfur and charcoal)

Expl As a matter of fact, black powder is used for various explosives. Add 5-10 % water in order to keep the substance under secure conditions. Never keep black powder in large amounts - for instance in metallic containers ! Use wooden barrels or a plastic bottle.

Deutscher Bildungsserver

Universität Frankfurt, Schauvorlesung

Schwarzpulver für Ihre Gesundheit

Schwarzpulver im Österreichischen Bundesheer :
"Viele Versuche mit Schießpulver erbrachten 1425 das "Nürnberger Rezept" für Schwarzpulver, welches 6 Teile Salpeter sowie je einen Teil Schwefel und Kohle vorsah."
[Impressum: Eigentümer und Herausgeber
Bundesministerium für Landesverteidigung
Roßauer Lände 1, 1090 Wien
Kontaktaufnahme]

manganese oxides
dimangane heptoxide
[Mn2O7]

 

Ingredients:
KMnO4, H2SO4

Explosive dark metallic greenish-brown oil. Evaporates at a temperature of 40-50°C.

Reaction / decay (40-50°C):
2 Mn2O7 --> 4 MnO2 + 2O3 (ozone)

Expl Beware of the temperature rising above 40°C ! This agent is a good example for reactive compounds.

hexogen
[??????]

Risky explosive,
used for rocket propulsives, artillery, underwater projectiles.

(experienced by Christoph L. and Stephan Simon)

Ingredients:
??????????
Expl
Toxic
Today, hexogen is recognized as an important military explosive being chemically stable and having a good handling.

Deutscher Bildungsserver

Smoke Bombs Ingredients:
KNO3, sugar

A relatively cheap and simple smoke mixture is potassium nitrate (saltpetre) and sugar. The mixture can be used in powder form, but much better results are achieved by melting the components together. The mixture should be heated slowly until it just melts !

The mixture does not have to be completely liquid, the point at which it has about the viscosity of tar or cold honey is about right. While it is semi-liquid it can be poured into cardboard or clay molds, and a fuse inserted. Once it cools and hardens it will be similar to a stick of hard candy, hence its common name of "caramel candy".

Expl
Oxid
The mixture should be heated slowly until it just melts - beware of excessive heating as the mixture will ignite. Keep a bucket of water next to you in case the mixture does ignite, and peform the entire operation outdoors if possible.

The mixture burns very hot. Don't go near it once ignited, and don't assume that whatever the mixture is contained in or standing on will survive. Do not try to breathe in the smoke as fine particles in the lungs are not good for them.

Burning powder

This substance burns up quickly with a bright flame.

Ingredients:
KNO3, S, icy sugar (confectioner's sugar)

Mix potassium nitrate, sulfur and icy sugar in a ratio of 1:1:1 (volume declaration).

Oxid Keep the substance under secure conditions. Never keep burning powder in large amounts.
White Fire

Burns up with a dazzling white flame

Ingredients:
??????????
Toxic "Realgar" (As2S2 - an arsenic sulfide) and "Arsenik" (As2O3) are both highly toxic. Beware of the generated arsenic gases (2 As2O3 <=> As4O6), they are color- and odourless.
Military smoke
powder

Releases vast amounts of smoke.

Ingredients:
??????????
Military smoke powder can cause eye-, pulmonary- and mucous mebrane irritation. Do not try to inhale the smoke as it contains harmful partciles.
Ethyleneglycol
dinitrate, Glycol
dinitrate

high-explosive dynamite, explodes more violently than nitroglycerin.

Ingredients:
??????????
Expl
Toxic
Glycol dinitrate is highly toxic and can be absorbed by skin easily. Handle this substance carefully because it is very volatile.

Glycol dintrate is also less sensitive to shocks than nitroglycerin making it more safe in handling. That is why it replaced its more dangerous forerunner effectively.

       
       

DISCLAIMER: Science-World is not responsible for the careless and unskillful use of the experiments listed above. It is highly recommended to use these techniques at maximum security. To avoid injure or harm just follow the rules of Secure Chemistry and use protective goggles + gloves and an overall.

NOTE: The author and editor of ScienceWorld is also NOT responsible for unexpected and instant injuries or terroristic crimes caused by the abuse of explosives and pyrotechnics. Thank you for your interest.

Pyrotechnics and explosives are not safe - factories have been destroyed in the past, and they have access to the best materials and equipment, and take the most stringent safety precautions. Some people on the net have also been injured by accidents, and many of them had years of experience and took extremely comprehensive safety measures.
Often you will see an interesting composition or method posted to ScienceWorld Chemistry and the temptation is to run out and try it immediately. However, sometimes information posted will contain errors, or omit important safety aspects. Sometimes people will post methods that they heard from some vague source, or that they think should work but haven't tried. It is essential that you read it several times to make sure you are completely familiar with it.

[ LITERATURE ]

Conkling, John A.: "Chemistry of Pyrotechnics: Basic Principles & Theory"
(Marcel Dekker, New York, NY 1986. (ISBN 0-8247-7443-4).

See also Conkling's articles in Scientific American (July 1990, pp96-102)
and Chemical & Engineering News (June 29, 1981, pp24-32).

Shimizu, Takeo: "Fireworks - The Art, Science and Technique", 2nd ed.
(Pyrotechnica Publications, 1988. (ISBN 0-929388-04-6).

Lancaster, Ronald: "Fireworks, Principles and Practice" (Illus.) 2nd ed.
(Chemical Publishing Company Incorporated, 1992. (ISBN 0-8206-0339-2).

Weingart, George W.: "Pyrotechnics" (Illus.)
(Chemical Publishing Company Incorporated, 1968. (ISBN 0-8206-0112-8).

Davis, Tenney L.: "Chemistry of Powder and Explosives"

SCIENCE-WORLD is published by Stephan J. Simon.